Polysulfide sealants and Ultraviolet radiation

Date: 17 May 2010
  • www.fenzigroup.com
Fenzi S.P.A. improves the resistance of the Thiover line

Thiover has always been the most successful Fenzi product, thanks to its simple use which allows it to adapt to all application methods, from robotic to manual, and its numerous attributes:

- mechanical properties with high elastic moduli designed for optimal preservation of the first-barrier sealant’s functionality, and thus the seal of the insulating glass;

- low permeability, to water vapor as well as gases;

- perfect adhesion to all types of glass and metal spacer bars;

- no danger for the operators or the environment.

Nevertheless, Thiover sealants belong to the family of organic products, and as such their primary "enemy” has always been ultraviolet radiation. As is well-known, the sun produces ultraviolet radiation. At altitudes above 80 km, the atmosphere completely absorbs only the wavelengths shorter than 200 nm, (UV limit), by interaction with the oxygen molecules still present at this height. Between altitudes of 10 and 50 km, on the other hand, the oxygen molecules disassociate (O2 → 2O.) and form molecules of ozone (O2+O. → O3).


Ozone, together with oxygen, is one of the main absorbers of ultraviolet radiation, but both fail to completely block its passage. Thus the radiation interacts with man and the environment. In the particular case of polysulfide sealants, the combined action of ultraviolet radiation, oxygen, heat and humidity represents a critical factor for the stability of the molecular structure, and the sealant may become detached from the substrate due to the breaking of weakened chemical bonds. The solar spectrum contains radiation in the ultraviolet field of various intensities and with energies comparable to the energies of some characteristic bonds of the polysulfide chain. The photochemical reaction mechanism involves the attachment of the atmospheric oxygen onto some carbon atoms of the molecular chain, with consequent oxidation and formation of hydroperoxides which are very sensitive to solar radiation.


The subsequent breaking of the hydroperoxides by the UV solar radiation forces the chemical structure to restabilize by breaking the chain. As a result of this action, the sealant detaches from the glass substrate more easily following the traction and/or tangential stress characteristic of the insulating glass’s natural movement. Despite the fact that the Thiover sealants’ field of use is specifically limited to situations in which there is adequate protection against UV radiation, and thus the process described above is drastically minimized, Fenzi S.p.A. has nevertheless identified numerous determinant factors supporting investment towards a decisive improvement of the product:

1. A general increase in the ultraviolet radiation which, due to reflection and refraction, reaches the edge sealant of the insulating glass, as a result of both climate and design changes. Unfortunately, in the mid 80’s the scientific world made one of its most important and disturbing discoveries: the shrinking of the ozone layer over the Antarctic region, due mostly to the use of chlorofluorocarbons (CFC), in combination with climate changes has led to an increase in ultraviolet radiation. The new parameters required by the building industry regarding improved energy efficiency are encouraging the design and use of doors and windows with minimized heights that reduce the thermal transmission (Uw) of the window but expose the sealant to greater amounts of ultraviolet radiation.

2. The desire to protect our customers through improvement even when the insulating glass has not been installed up-to-standard, thus increasing the exposure of the Thiover sealant to the combination of risk factors cited (ultraviolet radiation, heat and humidity).

3. European Regulations and Voluntary National Marks.

Since the beginning of its drafting and approval, the European Community Standard EN 1279-4 which determines the minimum resistance for the sealants used in our sector has been considered by many operators as unable to guarantee long-lasting life of the products under the action of ultraviolet radiation. In fact, it requires verification of the mechanical properties and adhesion to the glass after a UV exposure of only 96 hours without the presence of humidity.

Some European countries like France and Belgium virtually allow, through Voluntary National Marks, the use of only those sealants that have passed decidedly much more rigorous ageing tests. In fact, the FENZI S.p.A.’s minimum requirements for Thiover sealants have always been based precisely on these tests, using them continuously as a test bench for the improvements which we will describe in this article.


FRANCE – CEKAL Mark (Method NFP78-451)

This test includes the combined action of heat, humidity and ultraviolet radiation for 6 weeks and the determination of the load values and deformation after traction. The traction data according to CEKAL regulations indicate that, with practically the same starting point in terms of normal load (tensile stress) and deformation (tensile strain) characteristics, at the failure for glass-sealant-glass samples, the UV conditioning is supported better by the THIOVER 2010 product than the standard. In particular, it goes from a load/deformation ratio just above the AB limit line to values far beyond the limits imposed by the test.

The following bar graph shows the differences for the tests carried out on THIOVER and on THIOVER 2010:

To confirm an effectively improved resistance to the radiation in the presence of heat and humidity, the different types of failure on the substrate at the end of the traction (failure of the sealant) have been compared: In most of the tests, even though THIOVER always remains for the most part attached to the glass, the thickness of the material is very similar to a skin.

A film-type failure such as that in the figure shows that the attack by the UV radiation in conjunction with the other agents (heat and humidity) occurs mainly near the substrate. The chemical bonds break more easily since they are not supported by more efficient stabilizers and/or UV retardants.

In the case of THIOVER 2010, the enormous work of the anti-UV agents included in the formula guarantee a better barrier against the radiation. The sealant fails a few millimeters from the surface, indicating that the bonding is stronger near the substrate. Furthermore, the surface detachment areas show the presence of residual sealant.


BELGIUM – BCRC INISMA Mark (Method UBAtc 04.03.C)

This test includes the combined action of heat, immersion in water and ultraviolet radiation for one week and the comparison of the failure load values obtained before and after ageing. These limits must not be less than 30% the initial characteristic values of the sealant. The type of failure from the substrate is also evaluated.

This test, unlike the CEKAL procedure, includes tangential traction (shear stress) for samples glued onto various substrates (glass-glass, galvanized steel-glass and aluminum-glass). The graph below illustrates the traction data obtained according to the UBAtc procedure (BCRC INISMA) for the Thiover standard and Thiover 2010.


In this case the improvements obtained with Thiover 2010 are even more evident. The new product does not undergo any alteration following exposure to the ultraviolet radiation and the failures on the various substrates remain around 100% cohesive (no loss of adherence). The test case including tangential stress also highlights the stronger and longer-lasting UV resistance of the THIOVER 2010 sealant.

Over the years, Fenzi Research’s efficient work has led to continuous improvement of the sealant’s performance in terms of mechanical and adhesive properties as well weatherability. Recently, in compliance with the revisited and stricter requirements of the market and certifying bodies for products with greater resistance to UV ageing, additional efforts have been made in the study of additives and agents that can be used in the THIOVER formulation.

A thorough and careful screening during the experimental phase of products such as UV retardants, UV stabilizers and UV absorbers has provided the breeding ground for improvements in the anti-UV characteristics of THIOVER sealants, today and tomorrow. . .


About Fenzi Group

The Fenzi group started out in Milan in 1941 during the War, when Otello Fenzi, a chemist already working in glass, decided to start his own business. The first plant made coatings for mirror glass, products which were to allow the firm to grow for the next fifty years.


The impressive growth of the first thirty years.

From the 1950s onwards Fenzi began also to sell accessories, as an all-round service to the glassmaking industry. In 1968 production started on lead profiles covered with brass, for which Fenzi still today holds the record for volumes, extent of range and quality. The constant growth of the firm meant several relocations, until in 1972 the group moved to the Tribiano plants, location of the firm’s headquarters still today.


New product ranges.

In 1981, therefore, Fenzi decided to develop another product range, that of sealants, a decision which was to enable the group to approach the market of producers of double-glazing. The industry has expanded a great deal since the early 1990s, to the extent that it has become the most important for the Fenzi group in terms of volumes.


Alu-Pro comes into being.

In 1992 Fenzi, with reliable partners, founded Alu-Pro, a firm specialised in aluminium profiles for double-glazing and which today has plants in Italy, Denmark and Poland. The sealants-profiles synergy led to exponential growth of the sector, and nowadays Alu-Pro combines 250 million metres of aluminium spacers produced each year with steel and stainless steel profiles produced by Rolltech, a firm in Hiørring, Denmark, which it took over in 2001.

2002 saw the creation of Glass Alliance, a leading world network for products for insulating glass, set up by Fenzi with Alu-Pro and Rolltech. Fenzi has also extended its coverage of this market even further with the opening in 2004 of the Fenzi North America sealants plant in Canada, aimed at meeting the needs of the American continent.


New market.

In the 1990s another promising market was identified, that of enamel paints. The innovative paints of this kind produced by Fenzi are used worldwide in building, furniture manufacture and interestingly, as this is a new market for Fenzi, electrical household appliances. The use of glass is increasingly frequent in this type of product whose colouring requires the latest products.


Mirrors once again in the foreground

In 2004 Fenzi acquired from Akzo Nobel the business unit specialising in mirror coatings. The plants in Vilvoorde, Belgium, are equipped with high-tech systems, able to ensure the maximum quality standards. The acquisition was strategic, both due to the location in the heart of Europe and the specialization with producers of copper-free mirrors, the latest trend in the sector.

2006 marks another important stage: Fenzi, present in China since the early 1980s with its sales network, started to produce mirror coatings at a plant in the area of Shanghai in order to stay closer to the market of the future, that of the Far East.


Today and tomorrow

The group currently has 7 plants in Europe, America and Asia, its products can be found in almost every country in the world and it is world leader in chemical products for the processing of flat glass. What are the ingredients of its success? Focus, the pursuit of excellence and innovation, attentiveness to market needs, production synergies and efficiency and long-term strategic planning.

Source: Fenzi Group Newsletter

FENZI SpA Zona Ind. – Via Trieste, 13/15 – 20067 Tribiano (Mi) Web site: www.fenzigroup.com

Press Office: Francesca Solera Il Filo Rosso Solera & associati Via Panfilo Castaldi, 33 20124 Milano - Italy Ph. +39 02 29523341 francesca.solera@ilfilorossonline.it www.ilfilorossonline.it

600450 Polysulfide sealants and Ultraviolet radiation glassonweb.com
Date: 17 May 2010
  • www.fenzigroup.com

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